Thursday, September 19, 2019

Effects of Tourism on the Environment :: Cause Effect Tourism Ecology Essays Papers

Effects of Tourism on the Environment Tourism is a big part in not just the United States but in every countries economy. It is constantly growing and according to the United Nations World Tourism Organization there are more than 800 million people that travel either internationally or domestically each year (Goodstein C. Traveling Green. Natural History. Jul/Aug 2006; 115:16.). The world of tourism is always evolving the technology of travel has made it easier and more intriguing to travel. It is believed that the number of people traveling will grow by as little as 4% each year over the next twenty years. This means that the number of travelers a year could reach a staggering one billion people a year (Goodstein C. Traveling Green. Natural History. Jul/Aug 2006; 115:16.). The financial gain that comes of this is great for a country. In Rwanda for example they charge 375 dollars per person to go out and see the silverback gorilla that is indigenous to the area. This works out to be about 1 million dollars a year for the government to help deter the cost of damages that may be directly caused by tourism. Other countries that do this include the Galapagos Islands, which generates in excess of $38 million a year, and also in Belize the government uses a conservation tax of $3.75 for every foreign visitor leaving the country. The tax in Belize generates almost 750,000 dollars a year to help the government with conservation. With the advantages of financial gain come some drawbacks. The environment is said to take a big hit when dealing with the effects of tourism. There are a lot of things that are said to happen when dealing with the effects, anything from water in lakes being impure due to nutrients that may be added to it while people are swimming in it. The example that was used in the journals were the bodies of water around the Fraser Islands in Australia. It was said that tourists may be bringing nutrients in directly from another area (i.e. sand from another beach with different nutrient on their feet, or water with different nutrients in it). The other one that I find quite entertaining was nutrients that me in a humans urine that have a negative effect on the organisms such as coral, or fungi that are in the lake. (Hadwen L., Bunn S., Arthington, A,. Mosisch T.

Wednesday, September 18, 2019

Comparing Crime and Punishment and Notes from the Underground :: comparison compare contrast essays

Crime and Punishment and Notes from the Underground  Ã‚  Ã‚   Crime and Punishment and Notes from the Underground   Ã‚  Fyodor Dostoyevsky's stories are stories of a sort of rebirth.   He weaves a tale of severe human suffering and how each character attempts to escape from this misery.   In the novel Crime and Punishment, he tells the story of Raskolnikov, a former student who murders an old pawnbroker as an attempt to prove a theory.   In Notes from the Underground, we are given a chance to explore Dostoyevsky's opinion of human beings.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚     Dostoyevsky's characters are very similar, as is his stories.   He puts a strong stress on the estrangement and isolation his characters feel. His characters are both brilliant and "sick" as mentioned in each novel, poisoned by their intelligence.   In Notes from the Underground, the character, who is never given a name, writes his journal from solitude. He is spoiled by his intelligence, giving him a fierce conceit with which he lashes out at the world and justifies the malicious things he does.   At the same time, though, he speaks of the doubt he feels at the value of human thought and purpose and later, of human life.   He believes that intelligence, to be constantly questioning and "faithless(ly) drifting" between ideas, is a curse.   To be damned to see everything, clearly as a window (and that includes things that aren't meant to be seen, such as the corruption in the world) or constantly seeking the meaning of things elusive. Dostoyevsky thought that humans are evil, destructive and irrational.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚     In Crime and Punishment, we see Raskolnikov caught between reason and will, the human needs for personal freedom and the need to submit to authority.   He spends most of the first two parts stuck between wanting to act and   wanting to observe.   After he acts and murders the old woman, he spends much time contemplating confession. Raskolnikov seems trapped in his world although there is really nothing holding him back; he chooses not to flee and not to confess, but still acts as though he's suffocation (perhaps guilt?)In both novels defeat seems inevitable. Both characters believe that normal man is stupid, unsatisfied and confused.   Perhaps they are right, but both characters fail to see the positive aspects of humans; the closest was the scene between the narrator of Notes from the Underground and Liza.   In this scene he almost lets the human side show, rather than the insecure, closed off person he normally is.

Tuesday, September 17, 2019

Complexometric Determination of Water Hardness Essay

Abstract The water hardness for unknown water sample number 40 was determined. From the results of the two complexometric titrations, the water hardness of the unknown sample was calculated to be 250.9 ppm CaCO3, which agrees with the ranges of acceptable water hardness in the city of Phoenix and Tempe Arizona. Introduction When rainfall picks up impurities from the soil, ions of sodium, magnesium, calcium, iron, and other metals are dissolved into the water. These impurities are what cause residues left on glassware from the reaction with the soap used for cleaning. Water hardness is from the metal ions with a +2 charge or higher being dissolved into the rainfall. When reporting water hardness, it is reported in units of mg CaCo3/L of solution, or in ppm due to one mg of solute having one millionth of the mass of a liter of water or dilute aqueous solution. It is reported using only CaCo3 because typically, Calcium is the largest contributor to the water hardness. The purpose of this experiment was to determine the concentration of metal ion impurities in an unknown sample of hard water by performing a complexometric titration with EDTA. The results were then compared to the expected range for municipal water hardness from multiple city websites. Methods All procedures from the CHM 152 Lab, Complexometric Determination of Water Hardness (1) were followed precisely. Unknown water sample #40 was mixed with approximately 20 ml of DI water, 3.0 ml of Ammonia/Ammonium Chloride (NH(aq) Buffer pH=10), and 4 drops of Eriochrome Black T indicator solution. It was then titrated with .004197 M EDTA, which was also made in the lab from 0.7582 g of , added to 500 mL of DI water, that was then standardized with a stock Calcium Ion Solution (CaCO(aq) 1.00g/1.00L) by titration. A total of 3 titration trials were completed to find the average molarity of the EDTA, and the average water hardness of unknown water sample #40. All mass measurements were taken from a AND Balance, serial number 12321601 and all titrations were done using a KIMAX buret, #173. Pipet measurements were taken from a 25mL Bel-Art, and 15mL Bel-Art pipet. The numerical techniques used in this experiment were, stoichiometry with mole ratio for calculating the molarity of the EDTA solution and water hardness and relative average absolute deviation in ppt to show how closely the results from the Standardized EDTA titration of each trial agree with each other. Data Analysis Based on the experiment and calculations, the average calculated concentration of metal ion impurities (water hardness) in unknown sample number 40 from this experiment was 250.9 ppm. From table 1, the average molarity of the titrated was calculated to be 0.004197 M. Table 1 The molarity of the EDTA solution for each trial n was calculated as follows: .0.01000 L CaCO3 SolnTotal EDTA Delivered LÃâ€"1.000 g CaCO31 L CaCO3 SolnÃâ€"1 mol CaCO3100.1 g CaCO3Ãâ€"1 mol Na2EDTA1 mol CaCO3=Molarity of Trial n The Average Molarity of the EDTA solution was calculated as follows: Average Molarity of EDTA Solution =Calculated molarity from each trialNumber of titration trials To determine how closely the results of each trial from the Standard Disodium EDTA titration (Table 1) agreed with each other, a relative average absolute deviation calculation was done. It was calculated as follows: Absolute deviation for trial n= Na2EDTA avg molarity-Total Na2EDTA Trial n absolute deviations3Na2EDTA avg molarityÃâ€"1000=Estimated Prescision (ppt) The results of the above calculation came out to be 14.45 ppt. With the expected range of precision being at most five parts per thousand, it has been observed that the molarity of the standard Disodium EDTA solution includes some obvious error. It seems that the observation of color change when Na2EDTA was titrated to the mixture of CaCO3, DI water, Eriochrome Black T, and ammonia/ammonium chloride was the most error prone. Not knowing when to stop titrating the EDTA solution, would have accounted for a misreading of measurement for the total volume of EDTA solution added to complete the titration, making the final molarity for that trial less than what was expected. Table 2 Based on the molarity results from table 1 and the data from table 2, the average calculated water hardness of unknown water sample 40 was calculated to be 250.9 ppm CaCO3. The water hardness of unknown water sample 40 for each individual trial was calculated as follows: =Total EDTA soln Delivered L0.02500 L CaCO3 solnÃâ€"0.004197 mol EDTA1 L EDTA solnÃâ€"1 mol CaCO31 mol EDTAÃâ€"100.1 g CaCO31 mol CaCO3Ãâ€"1000mg1.0 g Average Water Hardness (ppm)≠¡mg CaCO31 L CaCO3 Interpretation of Results Based on the data, the calculated water hardness of the unknown sample number 40 (250.9 ppm), is within range of the city of Phoenix’s calculated range of 164-291 ppm (2) and the city of Tempe’s calculate range of 150-400 ppm (3). References 1. Complexometric Determination of Water Hardness, Procedures, Mesa Community College CHM152LL website, http://www.physci.mc.maricopa.edu/Chemistry/CHM152/index.html, accessed 9/7/2013. 2. City of Phoenix website. http://phoenix.gov/waterservices/quality/index.html, accessed 9/8/2013. Copyright 2013 3. City of Tempe Az website. https://www.tempe.gov/index.aspx?page=1289#Hardness, accessed 9/8/2013. Copyright

Monday, September 16, 2019

Wired Communication Media

Abstract Tons of data is transmitted on day to day basis from one point to another. Data comes in all various forms, physical and virtual. All different application comes with different requirements for data transfer. There is lots of data sitting at one place that needs to transmitted for various different purposes So, there is a definite need of transmitting data. Author in this paper is attempting to address all the possible available wires and cables in the wired communication media for transmission.Author will also be analyzing their history, invention, types, categories, applications, advantages and disadvantages of the transmitting channel available. Keywords: Data, Signals, Wires, Cables, ? Introduction Communication has been around since the beginning of the mankind in one form of another. Its existence is been recognized even before formal language came was formed. People have been communicating through various different vocal indications, signals and gestures. Almost all o rganization in the world relies on data and signals in some form of the other to run their regular operations and accomplish their goals.Data comes in all forms physical and virtual. Businesses need data, its transmission and storage for smooth functioning. The main concern is transmission of virtual data from one machine to another. This can be for various discrete reasons such as read-only, modifications and updating. Thus, a reliable means of communication is needed for transfer of data (William & Sawyer, 2007). There are plenty different kinds of communication media (channels) currently used to satisfy the growing needs of people. Communication media is largely divided into two groups wired media (conducting media) and wireless media.Wired media provides a path for the signal through wires (optical fiber is also included). It was the wired communication media which pioneered in transforming the way the people talked to one another over greater distances or through previously imp enetrable barriers. In wireless media, the communication medium is either air or the atmosphere or space through which the signal travels. Although the current trends are increasingly moving towards use of wireless communication systems but wired systems are still as elevant as they possibly have been because wires still an important element in achieving high speeds for both data and signal can either analog or digital. (Ray & Acharya, 2004). Need for Data Transfer In today’s data driven world, there is no cap on form or type of information that needs to be shared between employees, business partners and clients. Organizations just cannot trust anyone to handle their most sensitive data. Thus, a secured passage for data transmission from one device to another is certainly critical.Data usually is collection of lots of forms of information which needs to be stored and maintained for several as per needed purposes. It is normally stored on disks and tapes but when it needs to t ransmitted it needs to be converted into signals for transfer. In order for the travelling signals to transmit, there are different types of media available to facilitate communication. A type of them, wired media are briefly explained in the following section of this paper (Kittler , 1996). Wired Communication Media – Wires and CablesWired communication media typically refers to data transmission over a wire based communication technology. Wired communication generally refers to physical cabling within a network where the signals are transmitted onto the physical medium i. e. wires. These wires are no longer made up of metal, but glass. These are also called as conducting transmission technologies such as telephone network, internet access, cable television and fiber optic communication. Electromagnetism which is wave guide used for high power applications is also considered as wired line.Alternatively, transmissions of data which don’t rely on wires (cables) are cons idered as wireless communication technologies (William & Sawyer, 2007). There are several different conducting transmission technologies presently available for data transmission. Network requirement for each application can be different, so choosing the right type of transmitting media is very crucial. The different conducting media are discussed as below: Twisted pair wire It was invented by Alexander Graham Bell in 1988. A twisted pair wire is made up of a pair of conducting copper wires twisted with each other over nsulation. The number of twisted pair wires within the outer insulation varies. The reason it’s called twisted wire because the two wires are insulated to prevent wire crossing are primarily twisted together. The twist and the outer insulation help to reduce lines from not only crossing and interfering with each other but also regulate the self and mutual induction. When two wires are running parallel to each other carrying a signal, the possibility of inductio n between them increases. When you hear else’s conversation while being on phone with your friend is a perfect example of it.This is called as crosstalk due to inductions. Such crosstalk is very low in lines passing perpendicular to each other. Thus, lines are twisted to avoid running parallel to each other as perpendicular is quite impossible. There are 7 different types of twisted pair wires available which are further divided into 7 categorized which are described as follows: †¢CAT – 1: Basically used to transmit analog voices. Provides speeds up to 1 Mbps. There used over the years has decreased drastically. †¢CAT – 2: It is almost identical to CAT- 1, but has slightly better performance in terms of attenuation.This kind can transmit data up to 4 Mbps. †¢CAT – 3: It provides speed up to 10 Mbps but the signal attenuates after distance of 100 meters. To mitigate this problem, a repeater can be used to transmit data over 100 meters with l ow attenuation. †¢CAT- 4: It provides speed up to 20 Mbps but they can transmit data only within 100 meters without much attenuation. †¢CAT- 5: With greater number of twisted pairs, they can transmit data at 100 Mbps providing much better quality of wires as compared to previous versions. †¢CAT- 5e: They can transmit data at 125 Mbps but can support up to 1000 Mbps on certain cases. CAT- 6: Their cost is almost same as prior categories but can provide speeds up to 200 Mbps. †¢CAT- 7: These category wires are heavily shielded but are rarely used because of their exceptional high costs. They can support higher speeds of 600 Mbps. Twisted pair wires can also further be classified into shielded twisted pair and the unshielded twisted pair. Shielded twisted pair carries an extra shield of insulation on top to avoid any external induction. All of the categories except CAT- 7 are available in both types.The reason CAT- 7 only comes in shielded form only due to its excep tionally high number of twists. It is been estimated that only a whole twisted pair wires can better serve a local area network of 100 meter range, being cost effective. Applications can be: †¢Computer networking †¢Ethernet cabling †¢Video applications such as security cameras †¢Telephone lines ? Coaxial Cable Coaxial cable was initially founded in 1929 but first used by AT&T in 1940. It consists of single copper wire which is surrounded by at least three layer containing an insulating material, braided wired and plastic coating.It conducts electrical signals via an inner conductor also called as main conductor usually made up of copper or stranded copper wire. This main conductor is a straight wire surrounded by dielectric which actually separates inner main conductor and outer metallic shield. The outer metallic shield is typically made up of from 1 to 4 layers of metallic braid and metallic plate reducing the attenuation by obstructing the outer inducing field s from reaching the inner main conductor. This functionality of coaxial wires allows transmitting analog signals over a broad range of frequencies.The final third layer protecting main conductor is jacket made usually up of thick plastic material. (Nahin, 2002) Please refer to figure 2 in appendix showing a coaxial cable construction with main conductor, dielectric, shield and jacket for better understanding. Coaxial cables are classified into two major categories depending upon the type of data they can transmit. These are: †¢Baseband coaxial cable: Thin baseband coaxial cables are usually used in local area network connecting computers and mainframe computers. They carry one way digital data at speeds up to 10 Mbps. †¢Broadband coaxial cable:Thick broadband coaxial cables are used to transmit analog signals mainly television signals are used to transmit analog signals. A certain disadvantage is even a small continuous current along the imperfect placed shield on any coax ial cable will cause visible or audible interferences. But, there is a major disadvantage using the above discussed two types of coaxial cables that is data theft. Data travelling through these types of wires can easily be trapped. However, fiber optic cables can be used to eliminate this problem. Fiber Optic Cable Fiber optic has made tremendous technological advances to transmit information in the last decade.Telecommunication has been completely revolutionized by this innovated material. The telecommunications currently use electricity, radio or light to send data, images and sound. Fiber optic cable is made up of nothing but a thin glass tube which covered with a plastic shield. It transmits data in form of light pulses instead of sound waves without any interruptions. Since the information is transported in form of light and not electricity, this completely disregards the possibility of degradation of signal and interference due to electrical noise.The photo diode on one cable end produces photons which travel at high speeds up to 100 Gps through the glass tube before it is collected by the photo receptor on the other receiving end of the cable. The fiber optic cable is made up of one or many thin fibers of glass or plastic of 50 to 125 micrometers in diameter which is approximately equivalent to thickness of a hair. It has a cylindrical region called nucleus which allows light propagation and the external zone of coaxial nucleus is called as coating, a plastic like cover. Please refer to figure 3 in the appendix for better understanding.The main advantage of using fiber optic cable is it does not facilitate data tapping and is capable of producing high speeds, over long distances with very low attenuation as compared to other wired cables. For example, it is capable of transmitting an encyclopedia set equivalent to 40 million words in one second. However, there is some attenuation caused due to reflections and refractions of the photons over the glass tu be. Fiber optic cables tend to be expensive but with the availability of cheap LED’s and photo diodes, make it much economical. There are basically two types of fiber optic cables: Single mode fiber – It facilitates data transmission with great speed over long distances. †¢Multi-mode fiber – They are further classified into two types: oMultimode step-index fiber: It is used to transmit data over short distances and in the conventional transference of images. oMultimode grated-index fiber: It is optimal medium to transmit data over intermediate distances. It has a refractive index of nucleus which gradually moves towards outside from center. Photonic Crystal Fiber Photonic crystal fibers were founded by the research group of Philip St. J.Russell in the 1990s. They are generally constructed with the same methods as optical fibers. It is a honeycomb structured wires where the glass tube containing holes carry light signals 10 times longer as compared to fiber optic cable (Dr. Paschotta, 2012). Please refer to figure 4a and 4b in appendix for better understanding. Photonic crystal fibers are mainly divided into two major categories: †¢Index Guiding fibers which has a solid core. †¢Photonic Bandgap or air guiding fibers which have periodic micro-structured elements and a core of low index material (e. g. ollow core). Applications for photonic crystal fibers include: †¢Fiber lasers and amplifiers which include high power devices. †¢Fiber optic sensors of several different kinds. †¢Telecom components such as dispersion control, filtering and switching. †¢Quantum optics. †¢Also for various other purposes such as spectroscopy, metrology, biomedicine, imaging, industrial machining, and military. Conclusion So far in this paper, author showed us the working, application and pros and cons of various wired transmission media. Nobody can decide the right medium on behalf of anybody.It really comes down to speed co st, availability, current system requirement, its integration and future upgrade for growing needs for any particular user. All this requirements are analyzed before any wiring installation is done. Hence, selection of wires according to their functionality plays a very important role in constructing a reliable network. Remember: Communication technology is always developing and you will always find new stuff for various purposes, so plan and select accordingly. ? References Dr. Paschotta, R. (2012, Sep 20). Photonic crystal fibers. Retrieved from ttp://www. rp-photonics. com/photonic_crystal_fibers. html Kittler , F. (1996). Journal of the history of communication media. Arthur and Marilouse Kroker Editors, Retrieved from http://hydra. humanities. uci. edu/kittler/comms. html Nahin, P. J. (2002). Oliver heaviside: The life, work, and times of an electrical genius of the victorian age. New York, NY: The John Hopkins University Press. Retrieved from http://books. google. com/books? i d=e9wEntQmA0IC&printsec=frontcover&source=gbs_ge_summary_r&cad=0 Ray, A. K. , & Acharya, T. (2004). Information technology: Principle and applications. 2nd ed. ). New Delhi, India: Prentice Hall of India Private Limited. Retrieved from http://books. google. com/books? id=iim25OLcUdYC&printsec=frontcover William, B. , & Sawyer, S. (2007). Using information technology. New York, NY: The McGraw-Hill Publishing Inc. Retrieved from http://books. google. com/books? id=WsAgAQAAIAAJ&q=William. B & Sawyer. S, 2007. Using Information Technology. The McGraw-Hill Publishing Inc: New York). &dq=William. B & Sawyer. S, 2007. Using Information Technology. The McGraw-Hill Publishing Inc: New York). &hl=en&sa=X&ei=v1kYUfO7G9Ot0AHJzYDgDw&ved=0CFYQ6AEwBQ

Sunday, September 15, 2019

History/Summary of Barcelona Wine Bar & Restaurant Essay

When Andy Pforzheimer was in college, he took a road trip to New Orleans that would change his life. While discussing the city’s eclectic dining with locals, a chef challenged Pforzheimer to go to France to discover what cooking is all about. Decades after listen to the chef’s word, Andy Pforzheimer is a renowned chef cause he has been a restaurant professional for over 30 years. He owned his own catering and consulting business. After that he opened the first Barcelona Wine bar & Restaurant become Co-founder, a collection of seven wine and snack bars in Connecticut and Atlanta. A graduate of Harvard University, he is responsible for the company’s overall growth and execution. Barcelona Restaurant Group proud itself on being â€Å"anti chain,† means different place different foods and serves. When customers dine at any Barcelona Restaurants, they will experience the local color and personal touch of neighborhood eatery in Milan, SoHo and so on. At Barcelona, life is all about authentic cuisine, excellent service and good time. In order to delivering the special dining experience, Barcelona Restaurant Group realizes requires a unique approach to restaurant management. Barcelona Restaurant Group gives employees the freedom and control they need to imprint customers. The mutual trust Barcelona places in workers is obvious during weekly staff meetings. They will share the info/knowledge or argue with someone like employees argue with managers during weekly staff meetings. Andy Pforzheimer always mixes it up with employees, and the dialogue gets touchy at times. He said that he interested in having other people’s opinions thrown at him, like managers who talk back, and like people who self start. Besides, Scott Lawton, Barcelona’s chief operating officer(COO) that joined In 2006. With its corporate office based in South Norwalk, CT, Scott helps oversee the development, day to day operations and personnel recruitment for the restaurant’s seven locations. He underscores that Barcelona’s success depend on the mature initiative of employees. It was because, we just give some basic guideline as to what our philosophy is what our beliefs are, but we have to trust the employees to work within those limit and make the correct choice. In refusing to micromanage every single behavior of employees, Barcelona willing to take risk to give power to the employees and allowed them to make decision that other restaurant establishment would rather prevent. Lawton known that you are actually limiting your ability to get better because they might not always make the choice that I would make, but sometimes they will make the better one. To give the employees a right answer to every question is impossible. While the Barcelona’s concern about the wait staff, they make the staff clear customer is the primary concern, everything else is secondary to that. Lawton agrees and he adds that Barcelona’s insistence on service rarity leads to high contentment among employees. In conclusion, if we can empower employees to make guest satisfaction, they are going to earn money, the vibe of restaurant is going to be a ton of fun, everybody’s going to enjoy the work, and they are happy, because that is a byproduct.

Saturday, September 14, 2019

Bhopal Disaster

The night of 3rd December marked an industrial disaster when more than 40 tons of methyl isocyanate gas leaked from a pesticide plant in Bhopal, India that instantly led to the death of approximately 3,800 people and causing permanent injuries for thousands more. The company involved shamelessly tried to avoid its legal responsibility. Nonetheless, a sum of $470 million was paid as compensation, a considerably small amount in comparison to the impact from the consequences of this tragedy.The aftermath of the disaster indicated the need for international standards for environmental safety and preventive strategies to sustain from similar accidents. India has experienced rapid industrialization since the disaster. Despite some positive changes to government policies and behavior in several industries, rapid and poorly regulated industrial growth still remains exposing India to a major threat. Degrading of environmental practices with adverse consequences to human health continues to oc cur throughout India. 2. IntroductionThe Bhopal disaster, also known as the Bhopal gas tragedy was an industrial disaster that took place at the Union Carbide pesticide plant in the Indian city of Bhopal, Madhya Pradesh releasing tons of toxic chemicals and gases. This report is carried out with the objective of obtaining sufficient knowledge of the entire tragedy that took place and providing a detailed substantive summary of the mishap. Firstly, objectives and the management structure of the Union Carbide are discussed in this report to gain an overview of the company involved and its practices.Subsequently, an observation is done with regards to the industrial processes and operations of the plant to understand the on goings of the plant. The critical area of this report summarizes the key risks and contributing factors that ultimately led to the accident which provides an insight of the flaws in the plant. The consequences of the aftermath are then identified to provide an overv iew of the negative impact resulting from the disaster followed by a brief discussion on the improvements that should be done in the management systems to prevent similar accidents from happening in the near future. 3.Objective and Structure of the Management The Union Carbide India Limited (UCIL), a chemical factory which formed its establishment in 1969 near Bhopal, Madhya Pradesh in India and was owned by Union Carbide Corporation (UCC) and the Indian authorities. Pesticides such as carbaryl was produced in this plant and in 1979, a new addition was made whereby the methyl isocyanate (MIC) plant was introduced to the site. Prior to 1979, the methyl isocyanate was imported from its parent company in the United States and India was one of the three dozen countries whereby the parent company had affiliates and business interest.It was stated that the UCC had done extensive research on the chemical and had sufficient knowledge on handling the chemical. Methyl Isocyanate, one of the m any intermediates used in pesticides is known to be a very hazardous chemical which weighs much lighter than water but twice the weight of air. In the event that the gas escapes to the atmosphere, it will remain close to ground and this highly sensitive chemical can react with many substances which could cause serious damage.UCIL was proud to celebrate its 50th anniversary in 1984 and was making sales of approximately $200 million annually whereby 14 plants were being operated and it was segregated into 5 operating divisions making it a diversified manufacturing concern. The shares were publicly traded on the Stock Exchange 24% of these shares were owned by government run insurance companies whilst 50. 9% of the shares were owned by UCC as part of a corporate global business strategy. http://www. wikipedia. org/bhopaldisaster Due to its centralized location in India which gave it a competitive edge, Bhopal was chosen as the site for the UCIL’s plant.Transporting products were eased by the existence of railway systems that spanned around the country which evidently brought to extensive cost savings. Furthermore, the location of the plant being situated nearby a large lake guaranteed sufficient water supple for the chemical processes. Electricity needs were also available in Bhopal to supply enough electricity to the plant that enabled the plant to operate 24 hours. The origin on the Bhopal plant was to supply pesticide in order to protect the Indian agricultural production.These pesticides were made to cater to the Indian market and to gain the ability to transform its agricultural sector into a modern activity. No doubt the benefits, the plant also had its perks. India is still nonetheless a developing country which at current still lacks the infrastructure necessary to support this chemical plant. Nevertheless, companies invested in the plant failing to realize the flaws in the infrastructure. The impracticality of the plant’s management brought the creation of a low cost plant with minimal safety features. UCIL also had weak policies, procedures and regulations for their workers.The management’s goals and missions were set beyond the plant’s capability and this is said to be one of the main causes of the tragedy. 4. Industrial Processes and Operation Union Carbide is a known plant that produces the pesticide plant in the Indian City of Bhopal, Madhya Pradesh for agriculture purposes in India. Using MIC as an intermediate, an alternative trademark brand name for carbaryl is also known as Sevin. Until 1979, MIC was imported from the United States of America. Bayer, another known manufacturer successfully produced carbaryl without using MIC which evidently led to a greater manufacturing cost.Methyl isocyanate (MIC) is an organic compound that consists of molecules and in 1888, it was discovered as an ester of isocyanic acid. The production of carbate pesticides such as carbaryl, carbofuran, methomyl and aldicar b is an intermediate chemical of Methyl isocyanate. These pesticides were also being used in the production of rubber and adhesives. Methyl isocyanate is a very hazardous chemical which can lead to chronic diseases and death. The chemical process or route that was used in Bhopal plant was to form a reaction between the methylamine with phosgene which could bring to the production of methyl isocyanate.Subsequently, this methyl isocyanate was then reacted with 1 – naphthol to form the end product. This route varies from the MIC free route used elsewhere in which the similar raw materials are used but in a different manufacturing order. This process would begin by forming a reaction between the phosgene and naphtol to produce chloroformate ester which would then be reacter with methyl amine. Either one of these processes would require the chemicals to be stored in large tanks. In the operational side, the plant workers were encouraged to use English manuals, even though only a m inority of them had a grasp of the language.Only six of the original twelve operators remained in service with MIC by 1984. There were no personnel to take on the position of a maintenance supervisor to be placed on the night duty and furthermore, instrument readings were only taken every two hours which differs from the normal practice. Through a union, workers made a strike and complained about these difficulties but no attention was given to them. http://www. wikipedia. org/bhopaldisaster The refrigeration system was designed to inhibit the volatilization of MIC whereby based on the manuals, it was advised that the MIC should be kept at 20 degrees.However, since May 1984 this refrigeration system had been shut down in Bhopal. Current practice shows that the methyl isocyanate should be kept below 5C and should be checked on all the time. Steam boilers were also used for the purposes of cleaning the pipes. 5. Risks that Lead to the Accident Bhopal gas disaster was an industrial tra gedy that took place at a Union Carbide pesticide plant in the city of Bhopal, Madhya Pradesh. At midnight on 3rd December 1984, it was reported that the plant had accidently released Methyl isocyanate gas and this mishap was exposed to more than 500,000 people.Official death toll announced by the government of Madhya Pradesh confirmed that a total of 3,787 deaths were the result of this gas tragedy. Factors leading to this tremendous gas leak include the use of hazardous chemicals such as MIC instead of a less dangerous but more expensive chemical. It was also noted that the flare tower and the vent gas scrubber had been dysfunctional for the past 5 months before the disaster took place. This eventually led to the gas scrubber not performing its function to treat the escaping gases with sodium hydroxide that subsequently brought the concentration down to a safe level.Investigations in the aftermath of the disaster pointed out that even if the scrubber was in a good working conditio n, the disaster would not have been prevailed as the maximum pressure it could handle was only one-quarter of that which was present in the mishap. Improper designing of the flare tower itself contributed to the tragedy as the tower could only support one-quarter of the volume of gas that was leaked in 1984. Since the cease of production in the early 1980’s, the maintenance of the plant has continuously deteriorated up to an intolerable limit which resulted in the failure of several safety systems.The steam boiler which existed to clean the pipes was out of service for reasons which are unknown. Furthermore, the omission of the slip blind plates installation has played its role in causing this disaster. This omission had incidentally led to a large amount water from the pipe cleanings to leak into the MIC tanks through faulty valves leading the temperature to rise to a level whereby the tank was not designed to support that subsequently resulted in a large amount of toxic gas es to be released..The MIC tank itself has been malfunctioned for roughly a week which caused other tanks to be used in that week. Instead of taking corrective action and repairing the dysfunctional tank, it was just left to â€Å"stew†. Overall to conclude, the build up in temperature and pressure was strongly believed to be the cause in the magnitude of the toxic gas released. Economic conditions also played its part in contributing to this mishap. It was said that the leaking of the large amount of water into the MIC tank was also due to bad maintenance and leaking valves.The pipes were not repaired as it was believed to be very costly and time consuming. Safety systems including the MIC tank refrigeration systems were also shut down to in order to bring cost savings and it is of the opinion that the MIC refrigeration system alone would have prevented the tragedy from happening. http://www. wisegeek. com/what-was-the-bhopal-disaster. htm Material corroding that took place in the pipelines was also the contributing factor to this disaster. Carbon steel valves that were being used in the factory would corrode when exposed to acid.Based on investigations, a leaking of carbon steel valves was found on the night of the disaster. Overall, several factors led to this industrial disaster namely caused by poor maintenance and regulations. 6. Consequences of the effect of the accident The Bhopal disaster can be said to be one of the world’s worst catastrophe that took place at the Union Carbide pesticide plant in the city of Bhopal, India. On 3rd December 1984, the plant released MIC and other toxic gases exposing more than 500,000 people.The city of Bhopal was surrounded with a mixture of poisonous gases causing great panic as people woke up with burning sensations in their lungs. Based on the government of Madhya Pradesh, the effect of the hazardous gas had caused 3,787 confirmed deaths and leaving many trampled in panic. Other sources estimated that around 8,000 people died within the next 72 hours from gas related diseases and roughly 100,000 – 200,000 people are estimated to have permanent injuries at different degrees. http://www1. american. edu/ted/bhopal. htmMass funerals and cremations were taking place as well as disposal of bodies in the Namada River. The health care system became tremendously overloaded as approximately 170,000 people required treatments at hospitals and temporary dispensaries. Authorities had marked 36 wards as being â€Å"gas affected†. Acute symptoms from the gases are burning in the respiratory tract, eyes, breathlessness, vomiting and choking which ultimately led to death. Humans were not the only ones affected from this terrible tragedy. Approximately 2,000 buffaloes, goats and other animals’ carcasses were collected and buried.The effect on trees could be seen immediately as the leaves yellowed and fell of within a few days. Food supplies became scarce due to the fear being felt by suppliers. Further shortages were also caused once fishing activities was prohibited. http://www. bhopal. com/pdfs/browning. pdf Overall, this mishap has brought fear and has frightened many people as the Bhopal city was turned into a toxic city. A settlement was finally concluded in 1989, whereby UCC agreed to pay the Indian government a sum of $470 million in full and final settlement of its civil liability. After the lap f 25 years, 390 tons of toxic chemicals were left neglected at the plant which continued to pollute the ground water which affected thousands of residents who relied on it. 7. Improvements to prevent the accident Substantive investigations pointed out that the main reason which escalated this disaster is due to the management’s intention on reducing their expenses. The design of the plant had been modified by the Indian engineers in order to bring cost savings. This practice should be improvised and the plant should be designed thoroughly and prope rly to support the volume of production and the type of chemical produced.A contributing factor to the tragedy was weak management practices that should be made more stringent. A proactive policy should be adopted whereby dysfunctional items and parts of the plant should be fixed immediately instead of prolonging the situation despite it being costly and time consuming. Strict maintenance should be carried out on a routine basis and the MIC tanks should be continuously monitored to ensure that all processes are smooth going. Rules and regulations set for the plant should be adhered and complied to prevent any setbacks. ttp://www. wisegeek. com/what-was-the-bhopal-disaster. htm As the plant’s production involves a hazardous chemical, more experienced workers in dealing with such reactive chemicals should be hired instead on focusing on low labor cost. Trainings should be provided continuously to improve their expertise. Furthermore, extensive research and studies on how to han dle chemicals of this sort should be carried out prior to any processes to ensure that the staff has sufficient knowledge on what to do and what to expect.Despite sufficient trainings and research, mishaps can occur any at given time. Following that, it is always best to have a detailed contingency and back up plans in order to contain any rotten situation. A good practice is always to expect the unexpected in order to be ready for mishaps. This tragedy has affected the lives of many in the Bhopal city. It is recommended that such factories as this plant should not be located in residential areas and best located in the outskirts to prevent residents being exposed to toxic gases.Ultimately, this disaster would have been prevailed with good management practices, abiding to rules and regulations set and also focusing on safety systems instead of cost savings. http://www1. american. edu/ted/bhopal. htm * 8. Conclusion * The Bhopal gas disaster marked one of the most tragic accidents in the world. The pesticide plant in Bhopal, India was managed by UCIL, a subsidiary of the UCC, had begun the production of a hazardous chemical, methyl isocyanate in 1979. The findings from this research pointed out that UCIL had weak policies and regulations and was prioritizing more on cost savings at the expense of the plant’s safety. The operational side of the plant was suffering from lack of staff namely there was no maintenance supervisor responsible to monitor the MIC tanks. Furthermore, critical parts of the plants were being left unattended when it was dysfunctional due to it being costly and time consuming to repair. Safety systems of the plant were being comprised in order to reduce expenses. * * To conclude, the main improvement to be done is to emphasize on the plants design to support the volume and type of production.Stringent policies and regulations should be set and adhered to in order to prevent similar accidents. Management should divert from a cost savin gs mindset and priorities more on the plant’s safety systems. * Despite being 25 years since the incident, tons of toxic chemicals were still abandoned at the plant and continued to pollute the ground water that affected thousands of residents. Overall, this disaster has brought awareness that international standards for environmental safety should be enforced to prevent similar mishaps. .References 1. Bhopal disaster,online,retrieved 15 November 2009 from http://www. wikipedia. org/bhopaldisaster 2. Bhopal disaster, online, retrieved 15 November 2009 from http://www1. american. edu/ted/bhopal. htm 3. Jackson B. Browning 1993, Health, Safety and Environmental Programs Union Carbide Corporation, online, retrieved 16 November 2009 from http://www. bhopal. com/pdfs/browning. pdf 4. What was the Bhopal disaster, online, retrieved 18 November 2009 from http://www. wisegeek. com/what-was-the-bhopal-disaster. htm

Annie Oakley

The great Sioux warrior Chief Sitting Bull was so impressed by Oakleys skill that he adopted her, giving her the name Watanya CeciliaLittle Sure Shot. Though her life inspired dime novels, a Broadway play, and Hollywood movies, little is known about the real Annie Oakley, an intensely private, complicated woman who excelled publicly in a mans sport. (Foundation) Near the end of her life, Will Rogers paid her a visit and then wrote about her in his daily newspaper column: She was the reigning sensation of America and Europe during the heyday of Buffalo Bills Wild West show. She was their star. Her picture was on more billboards than a modern Gloria Swanson. It was Annie Oakley, the greatest rifle shot the world has ever produced. Nobody took her place. There was only one. (Edwards) Annie Oakley, an American Experience documentary film which aired May 8, 2011 on PBS, separates life from legend. Filmmaker Riva Freifeld says she was initially attracted to the project because I thought this was the most extraordinary story of somebody breaking out of a mold. A woman of the Victorian age, small, petite, who had a horrible, miserable childhood. She pulled herself out of all that through her own talent and worked through the pressures against women and made herself into the most famous practitioner of a sport that is quintessentially male: sharpshooting. (Vonada) Virginia Scharff, professor of history and director of the Center for the Southwest at the University of New Mexico, agrees. She is the epitome of the self-made woman. This is somebody who triumphs over about as miserable a childhood as you can imagine. You would never know that by looking at her public persona. She seemed like the all-American girl who must have grown up amid motherhood and apple pie, but the truth of the matter was that she grew up in the most abject kind of poverty. (Vonada) She was, hands down, the finest woman sharpshooting entertainer of all time. Oakley was always drawn to guns. Her father may have taught her to shoot when she was very young, and Oakley herself said that when she was barely big enough to lift her fathers old Kentucky rifle, she dragged it outside, rested the barrel on the porch railing, and shot a squirrel clean through the head. When Oakley returned home, instead of going to school, she earned good money by shooting game and selling it to the Katzenberger brothers grocery store, which shipped the game to hotels in Cincinnati. She was so successful that she was soon able to pay off the mortgage on her mothers house. She once remarked that from the age of ten, she never had money in her pockets that she had not earned herself. (Kim-Brown) In addition to game hunting, Oakley entered local shooting contests that were popular at the time, winning so many turkey shoots that she was eventually barred from them. But such was her reputation that when professional sharpshooter Frank Butler was passing through southern Ohio claiming he could outshoot anyone around, the locals accepted his challenge. They failed to tell Butler that his opponent was a teenage girl. I got there late and found the whole town, in fact, most of the county out ready to bet me or any of my friends to a standstill on their unknown,' Butler later said. I did not bet a cent. You may bet, however, that I almost dropped dead when a little, slim girl in short dresses stepped out to the mark with me. Butler lost, and gave Oakley tickets to his next show. ( Kim-Brown) According to Kim and Brown, a romance sprang up between the two and they were soon married. But it was six years before the shooting team of Butler and Oakley appeared. In the meantime, Butler traveled the variety circuit with his partner John Graham until one night when Graham became ill. Initially, Oakley acted as Butlers assistant, holding targets. But Butler was having an off night and he could not seem to hit his targets. Amid the booing, someone shouted, Let the girl shoot! Oakley calmly took the gun and hit every mark. Kim-Brown) Oakley was a natural performer. Modest, yet playful, she skipped onto the stage like a schoolgirl. She shot an apple from Butlers head, pierced the heart in the ace of hearts or, if the card was held sideways, sliced through it; she shot corks from bottles and blew out the flames from candles. She shot backward looking through a small mirror. She could shoot just as well with her left hand as with her right. Sometimes she pretended to miss and pouted, stamping her foot. At the end of her act, she blew kisses to the crowd and did a funny little kick as she disappeared behind the curtain. The audience loved her. (Kim-Brown) Frank Butler didnt mind fading into the background. Because he was so open-minded about women, says Freifeld, he basically created a situation where you had a role reversal of a typical Victorian marriage. I think Frank Butler understood that she had a kind of star quality that he didnt want to overshadow, says Scharff, and Frank Butler didnt have a problem with that. I think he adored her. I think he also was a savvy businessman who understood that she was pretty, she was ladylike, she was petite. She would do what needed to be done to make that rise to the top. And he didnt want to get in her way. As a matter of fact, he understood that for the two of them, the best thing possible was to let her take the lead. (Vonada) Annie, born Phoebe Ann Moses in Ohios Darke County on August 13, 1860, got her gun at an early age but didnt shoot her way to everlasting fame until after William Buffalo Bill Cody put her on the payroll in 1885. In the process, the little woman (5 feet tall, about 110 pounds) gave Codys Wild West a shot in the arm. As a star with the stature, ability and uniqueness of Buffalo Bill himself Annie Oakley had a platform to promote her egalitarian views about women. She believed that women needed to learn to be proficient with firearms to defend themselves and that they could even help fight for their country. During World War I, she offered to recruit and train a regiment of women sharpshooters. If nothing else, Annie Oakley helped expand the career options of American women. (Oakley, Annie. (2011). Britannica Biographies, 1. ) Annie Oakley rose to stardom from humble roots. In the mid- 1860s her father, Jacob, died, and her mother, Susan, had a devil of a time trying to make ends meet with seven children age 15 or younger on her hands. Annie Oakley tried to help by hunting and trapping in the Darke County woods. By age 10, Annie Oakley had been sent off to live at the county poor farm, known as the Infirmary, and during her early teens she alternated between living there and with her mother and stepfather. Her life took a turn for the better when she met Irishman Frank (Jimmie) Buffer of the Buffer and Baughman shooting act. Oakley, Annie. (2011). Britannica Biographies, 1. ) According to legend, Buffer was trying to drum up business in 1875 by accepting challenges from local marksmen, and on Thanksgiving Day in Greenville, Ohio, he took on young Annie Moses in a shooting match. I almost dropped dead when a slim girl in a short dress stepped out to the mark with me, Frank Buffer later said. I was a beaten man the moment she appeared. Frank lost, 23 to 21. Later, whenever he said that he had purposely thrown the match, Annie would just flutter her eyes and smile. In any case, Frank was impressed enough by Annie to invite her to see his act in Cincinnati. She accepted. As part of his act, Buffer and his big white French poodle, George, performed a William Tell bit. As usual, Frank shot the apple off Georges head and George retrieved the fruit, but the dog then brought it to Annie instead of to the shooter. A courtship ensuedbetween Annie and Frank, that isand the couple was married within the year or so the legend has it. (Oakley, Annie. 2011. Britannica Biographies, 1. ) Annie joined Franks stage act, according to her own account, only after Franks shooting partner, John Graham, became ill in May 1882. She filled in admirably and became an instant hit. She chose Oakley as her stage name for some unknown reason and began to tour with Frank. To the experienced showmans credit, he immediately realized that his wife was a star. He put his own career on a backburner so that he could manage her career, saying, She outclassed me. (Edwards) In those early days of her stage career, Annie Oakley played with Frank Buffer at small theaters, skating rinks and circuses. While working for the Sells Brothers Circus in New Orleans in 1884, they met Buffalo Bill Cody, but he didnt hire her until after she and her manager-husband had come to Louisville, Ky. , early in 1885 for a three-day tryout. After an agreement was struck, Buffalo Bill brought her to the mess tent to introduce her to the members of his Wild West, which had been inaugurated in 1883. This little missie here is Miss Annie Oakley, Buffalo Bill said. She is to be the only white woman with our exhibition. And I want you boys to welcome and protect her. They didnt need toLil Missie, as Cody usually called her, had pretty much fended for herself from childhood. (Edwards) Annie Oakley and Frank Butler toured with the Wild West for some 16 seasons, and the only contract they had with Cody was verbal. Annie said that Cody, whom she called the Colonel, was the kindest-hearted, most loyal man she had ever met, and also the softest touch. She noted that Cody kept a big pitcher of lemonade by his t ent so that he could serve refreshments to visiting youngsters. The Oakley act was spectacular. Cody generally used Lil Missie early in his entertainment extravaganza so that she could warm the audience up to the sound of gunfire. Dexter Fellows, a sometimes press agent for the Wild West, wrote in his autobiographical book This Way to the Big Show that Annie was a consummate actress, with a personality that made itself felt as soon as she entered the arena. During her entrance, Annie waved and blew kisses to the audience. She was an ambidextrous shot who fired rapidly and with unerring accuracy. On the rare occasions when she missed a shot, she immediately fired again. On occasion, she intentionally missed and then pretended to become petulant, stamping her feet in frustration and sometimes throwing her hat down and walking around it to change her luck. Then when she did hit the mark, the audience would roar louder than ever. (Edwards) Frank Butler also got into the act, releasing clay pigeons for his wife. She would jump over her gun table and shoot the clay bird before it hit the ground. Often she shot cigarettes out of her husbands mouth, and once she even shot a cigarette out of Kaiser Wilhelm IIs mouth. Charlatan shooters preferred to shoot ashes from cigars (with the help of a wire embedded in the cigar and twisted by the assistants tongue at the proper moment), so Annie insisted on shooting only whole cigarettes. Her act often included hitting targets while riding a bicycle with no hands. Although she could ride a horse in fine style, she left the shooting of glass balls from horseback to Buffalo Bill. Annie concluded her act with a funny jig and would kick up her heels just before she left the arena. Once when a newspaper in England wondered how fast and accurate she was, she gave a special demonstration. Frank stood on a chair facing his wifes back. At Annies command, he dropped a tin plate. Annie turned, fired and hit it square, all within about half a second. (Vonada) Annie Oakley had a theatrical flair and the quickness and agility of an athlete. But none of it would have meant too much had she not been such a top hand with all kinds of firearms. She practiced constantly and did not rely on trickery; she was no sham shooting star. Among her favorite shotguns were a Lancaster and a Francotte, her favorite rifles included a Winchester and a Marlin, and she used Colts and Smith amp; Wesson handguns equally well. Guns, rifles and pistols are of many styles, she once said, and to declare that any one make is superior to all others would show a very narrow mind and limited knowledge of firearms. Nobody should trust their lives behind a cheap gun. (Sorg) The famous Sioux (Lakota) spiritual leader and medicine man Sitting Bull toured with the Wild West during the 1885 season. Annie had a ctually met him the previous year in a St. Paul, Minn. , theater, when Sitting Bull, then a resident of the Standing Rock Reservation in Dakota Territory, watched her fire a rifle to snuff out a burning candle. Apparently, Sitting Bull was so impressed that afterward he asked to see the little white woman. Annie then gave Sitting Bull a picture of herself, while he gave her moccasins he had worn at the Battle of the Little Bighorn, as well as the nickname Watanya Cicilla (Little Sure Shot). They were happily reunited the next year as employees of Codys Wild West. Whenever Sitting Bull got peevish that season, Cody would send for Little Sure Shot, who would talk to the Lakota leader for a while and then do her jig before leaving his quarters. That inevitably would make Sitting Bull laugh and would lift his spirits. But her presence was not enough to make him want to continue with the show another season. (Sorg) In the spring of 1886, while the Wild West performed in Washington, D. C. , en route to an extended summer stay at Erastina, on Staten Island, an insect lodged itself deep inside Annie Oakleys ear. By June, she had an ear infection, but, against doctors orders, she still rode in the 17-mile opening-day parade in New York City. Near the end of it, she collapsed, and doctors determined that the area behind her eardrum needed to be lanced to drain its poison. The bedridden Lil Missie missed four performances at Erastina (probably the only four she missed during her show career) before she hobbled into the arena on the fifth day to shoot again. She had plenty of grit for sure, but part of Annie Oakleys motivation for getting back in action was the fact that Cody had hired a younger female shooter, Lillian Smith, for the 1886 season. At the time, Annie may have been concerned about her job security. But there was room for both of them, and the Wild West continued to be a big hit when it moved into Madison Square Garden that winter. (Oakley, Annie. (2011). Britannica Biographies, 1. ) On May 11, it was Queen Victorias turn to have a command performance. It was held at the exhibition grounds after her courtiers convinced her that they couldnt fit Codys outfit into Windsor Castle. When the American flag entered the arena, Queen Victoria stood up and bowed deeply, and Codys company roared its approval. For the first time in history, an English monarch had saluted the Star-Spangled Banner. After Lillian Smith and Annie Oakley had curtsied and walked up to her, the queen told Annie, You are a very clever little girl. Lil Missie had become an international star. At least one newspaper said that her marksmanship was better than that of Buffalo Bill. (Edwards) One notable wreck occurred at 3 a. m. on October 29, 1901, near Lindwood, N. C. , while the company was headed to Danville, Va. , for its last performance of the season. When the first section passed the switching station, the switcher thought that it was the whole outfit, so he threw the switch. The second section ran into an oncoming train. The wooden cars became so many piles of kindling as people and animals cried out in pain and steam hissed. Legend says that Annie Oakley, now 41, was found pinned beneath the rubble and it took several hours before she could be extracted. As Lil Missie was carried by stretcher past some wounded horses that had to be shot, she supposedly remarked that she felt sorry for them. Just 17 hours after the wreck, according to legend, her brown hair turned totally white because of the horror of the accident. (Edwards) After her retirement from the Wild West, Annie Oakley tried her hand at acting again, appearing as the lead in a play called The Western Girl, which opened in New Jersey in November 1902. She looked much as she had while shooting in the Wild West, except now she wore a brown wig to hide her white hair. She also would teach shooting at exclusive clubs. Meanwhile, her husband worked for the Union Metallic Cartridge Company, promoting its products to the growing number of trap shooters. In the spring of 1910, Frank and Annie attended a Wild West show at Madison Square Garden known as the Two Bills Show, because Buffalo Bills outfit had merged with Pawnee Bills outfit. Cody apparently asked Annie to rejoin the show, but she and Frank turned the old showman down. Instead, the following year, they joined up with Vernon C. Seavers Young Buffalo Wild West, and Little Sure Shot continued to shoot for that outfit until retiring for good in 1913. Annie and Frank continued to be friends with Cody, though, and when Buffalo Bill died on January 10, 1917, she wrote a glowing eulogy. (Edwards) After giving her last performance with Young Buffalo Wild West on October 4, 1913, Annie and Frank retired to a new home in Cambridge, Md. , and also spent a lot of their time at resorts in Pinehurst, N. C. , and Leesburg, Fla. Hunting and shooting remained a big part of their lives. They had no children. In the summer of 1922, when she was about to turn 62, Annie Oakley performed at a benefit show on Long Island (a clip of her performance that day can be seen at the Buffalo Bill Historical Center). The New York Herald hinted that she might be making a comeback in show biz and could appear in the movies soon. It never happened. That November, she fractured her hip and an ankle in a car accident in Florida. The steel leg brace she was forced to wear did not, however, keep her from resuming her shooting and hunting. (Oakley, Annie. (2011). Britannica Biographies, 1. ) The injury and time took their toll; four years later Annie went home to Ohio to die. She stayed for a while in Dayton, where humorist Will Rogers came to visit and found his old friend sitting up in bed. The next week, the Oklahoma cowboy reminisced about her in his newspaper column, asking people to write to the invalid who had once been the reigning sensation of America and Europe. (Edwards) By then, Annie surely must have felt obsolete. In 1894, she featured in one of the first Western movies, acting out her routines for Thomas A. Edisons kinetograph. Now screen stars like Lillian Gish and Gloria Swanson were all the rage, and no one wanted a star-spangled Western girl. Annie had her shooting medals melted down, sold the gold and donated the money to charity. (Edwards) She died in Greenville on November 3, 1926 (of pern icious anemia, according to newspaper reports).